The three-band model. Acoustic-phonon softening on cooling is observed. Superconductivity at 10.4 K in a novel quasi-one-dimensional ternary molybdenum pnictide K2Mo3As3, Synthesis and Exploration of the Lubricating Behavior of Nanoparticulated Mo15S19 in Linseed Oil, Dimensional crossover in the quasi-one-dimensional superconductor Tl 2 Mo 6 Se 6, Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials, Exploits, advances and challenges benefiting beyond Li-ion battery technologies, Phonon Dispersions as Indicators of Dynamic Symmetry Reduction in Superconductors, Small transition-metal dichalcogenide nanostructures down to subnanometer by two-dimensional material origami, Superconducting materials classes: Introduction and overview, Anisotropic upper critical field of pristine and proton-irradiated single crystals of the magnetically ordered superconductor RbEuFe 4 As 4, Doping-Induced Superconductivity in the van der Waals Superatomic Crystal Re 6 Se 8 Cl 2, Superconductivity in U-T alloys (T=Mo, Pt, Pd, Nb, Zr) stabilized in the cubic γ-U structure by splat-cooling technique, Expressand low-cost microwave synthesis of the ternary Chevrel phase Cu2Mo6S8 for application in rechargeable magnesium batteries, γ-U phase in UPt system retained to low temperatures by means of rapid cooling, Two-gap superconductivity in Ag1−xMo6S8 Chevrel phase, Intercalated Chevrel Phase Mo 6 S 8 as a Janus Material for Energy Generation and Storage, Advanced High Energy Density Secondary Batteries with Multi-Electron Reaction Materials, Structure, Electrical Resistivity and Superconductivity of Low-alloyed γ-U Phase Retained to Low Temperatures by Means of Rapid Cooling, p-block elements as negative electrode materials for Magnesium-ion batteries : electrochemical mechanism and performance, Phase stability and Raman/IR signatures of Ni-doped MoS$_2$ from DFT studies, Super Atomic Clusters: Design Rules and Potential for Building Blocks of Materials, Tuning Electron Acceptability of the [Mo6S8] Cluster Core by Decorating with Methyl Groups on Face‐Bridging μ3‐Sulfides, Intermolecular coupling and superconductivity in PbMo 6 S 8 and other Chevrel phase compounds, Exploring the Breadth of Terminal Ligands Coordinated in [Mo6X8]4+- and [Re6Q8]2+-Based Cluster Complexes, Mo 6 S 3 Br 6 : An Anisotropic 2D Superatomic Semiconductor, Doping-induced superconductivity in the van der Waals superatomic crystal Re$_6$Se$_8$Cl$_2, NaMoO 2 : a Layered Oxide with Molybdenum Clusters, Synthesis and superconductivity of a novel quasi-one-dimensional ternary molybdenum pnictide Cs 2 Mo 3 As 3, New Synthesis Route of PbMo6S8 Superconducting Chevrel Phase from Ultrafine Precursor Mixtures: I. PbS, MoS2 AND Mo Powders, Mg rechargeable batteries: An on-going challenge, Fully connected bulk Pb1−xSnxMo6S7.6 samples made by hot isostatic pressing, An anatomical study on the influence of various methods of operation for cancer of the rectum upon the pudendo-coccygeal plexus, NMR study of the influence of iodine substitution in the Chevrel comounds Mo6Te8-xIx and Mo6Se8-I-x(x), ChemInform Abstract: Rechargeable Magnesium Battery: Current Status and Key Challenges for the Future, Crystal growth and properties of Fe xMo 6S 8- y, High-Pressure Study of the Anomalous Rare-Earth Ternaries Eu1.2Mo6S8 and Eu1.2Mo6Se8, Observation of the Transition from Semiconductor to High-Tc Superconductor in (SnxEu1−x)yMo6S8 under High Pressure, Ion irradiation of Chevrel-phase BaMo6S8 films, Extreme type II superconductors: universal trends, Chemistry and Structure of Ternary Molybdenum Chalcogenides, Superconductivity in Ternary Compounds I; Topics in Current Physics, ChemInform Abstract: The Molybdenum and Rhenium Octahedral Cluster Chalcohalides in Solid State Chemistry: From Condensed to Discrete Cluster Units, Application of Solid-State Molybdenum Sulfide Clusters with an Octahedral Metal Framework to Catalysis: Ring-Opening of Tetrahydrofuran to Butyraldehyde. The 100th anniversary of the birth of Professor S A Altshuler, a pioneer in the use of NMR for studying Van Vleck magnetism, is a motivation for this review. It is shown that the instability can be observed even at relatively weak anisotropy. The Mo6S8 and Mo6Se8 clusters are quite similar to those in other compounds of this type. This article is cited by Rietveld analysis was also used to refine the structure of the unfilled phase MoâRuSeâ (R3-bar , Z=3, a=9.63994(8)A, c=10.97191(11)A, R{sub p}=8.0%, R{sub wp}=10.5%). While phase A showed a linear variation of Tac with c/a in the region from 11.0 to 13.0 K phase B was independent of the c/a ratio with a Tbc = 10.8 ± 0.2 K. The authors report, for the first time in the literature, crystal structure studies of rare-earth-based Chevrel-phase selenides of formulae LaâMoâSeâ with variable contents (x) of lanthanum. The results are consistent with the substitution of ruthenium or rhodium in the Mo6 octahedron within the Mo6Te8 unit. Using the magnetic field penetration depth λ determined by muon spin relaxation (μSR) measurements, we calculate the Fermi temperature TF of various superconductors. Clinical Trials Introduction biinoida. Mo6S8 (M, Cr, Mn, Fe, Ni; x: 1.3, 2.0) were prepared by reacting appropriate amounts of M, Mo, and MoS2 powders. the Altmetric Attention Score and how the score is calculated. Beyond the auride ion: triangulated gold networks and ethane-like structural units in binary and ternary alkali metal gold intermetallics. The most important physical behaviour is the extremely high initial slope of the critical field at Tc, which varies between 68kG/K and 78kG/K. Electron-beam-induced decomposition does occur slowly during observation, first disordering and then reducing the clusters, yielding regions of Mo metal or Mo-Ni alloy in the edges. Based on the creep results, we show that the second magnetization peak coincides with the elastic-to-plastic crossover at low $T$, yet the mechanism changes at higher temperatures. The lithium atoms in both cases are disordered over the two concentric rings of available tetrahedrally coordinated small atom sites. Your Mendeley pairing has expired. Furthermore, the thermal conductivity was dominated by the electronic thermal conductivity, and the complex crystal structure yielded a low lattice thermal conductivity. Topological Aspects of Chemical Bonding in Superconductors. This distribution changes drastically with cation insertion or partial chalcogen-halogen substitution, resulting in compound stabilization. While Cr1.3Mo6S8 crystallized in a triclinic structure, Mn1.3Mo6S8, Fe1.3Mo6S8, and Ni2.0Mo6S8 crystallized in a hexagonal structure. Numerous variants are found, from the binary material formed just by the molybdenum clusters Mo6X8 leaving a three-dimensional lattice where the third element M can be inserted, up to a condensation of clusters giving rise to a monodimensional material. Observation of this asymmetry in any superconductor would provide clear evidence for an unconventional order parameter. The highest critical fields Hc2(0) of 428 kG were obtained for Pb compounds. A possibility of a novel phase transition involving zero vorticity degrees of freedom and formation of a uniform condensate is suggested. Get article recommendations from ACS based on references in your Mendeley library. ChemInform Abstract: Synthesis of Cu2Mo6S8 Powders and Thin Films from Intermediate Oxides Prepared by Polymeric Precursor Method. The thermoelectric properties of this compound are compared to the previously reported data for other related Chevrel phases. The specimen consists of two phases, each showing threefold symmetry. The second phase, LT2, forms by a peritectoid reaction at 187 K and is stable in the range 3.1<×<3.3 while Tc decrease from 6.3 to 4.0 K. The rare earth molybdenum sulfides RExMo6S8 (RE = rare earth) have been synthesized and are found to be superconducting with a few exceptions. Electronic structure of Chevrel Phases: Emphasis on the part played by the cluster twisting angle through a LCAO-EHT tight binding study. These remarkable features are … These metrics are regularly updated to reflect usage leading up to the last few days. The superconducting temperature of this phase depends strongly on the lanthanum concentration, as they previously reported for powder samples. W. Bronger, J. Fleischhauer, H. Marzi, G. Raabe, W. Schleker, T. Schuster.

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