pulmonary edema, tachypnea, jaundice, hepatosplenomegaly, Lower explosive (flammable) limit in air (LEL), 1.79%; upper explosive (flammable) limit in air (UEL), unknown. a fish- or garlic-like odor, but may not provide adequate 0000140730 00000 n Do not direct water at the spill or the source of the leak. Technical Support Documentpdf iconexternal icon, NR = Not recommended due to insufficient data. to phosphides can also cause systemic effects. Odor: Disagreeable, garlic-like, or decaying fish odor when irritation, cough, and chest tightness. Sensors and Actuators B: Chem 7(1-3):727-729. Perform a thorough external evaluation and a preliminary identification check. irritation, CNS depression, and cardiovascular collapse. The agent may be ignited by heat, sparks, or flames. Aluminium phosphide is a yellow or dark grey crystalline solid that has a garlic-like odour. –87°C, dangerous level ca. However, if you have any health concerns regarding exposure to aluminium phosphide seek guidance from your GP or contact NHS 111. checking out the following Internet Web sites: 0000004081 00000 n 0000007526 00000 n Run-off from fire control may cause pollution. Chemical-resistant boots with a steel toe and shank. You or your physician can get more information on the Email: Contact CDC-INFO. Hand any evidence over to the FBI. 0000090800 00000 n Move containers from the fire area if it is possible to do so without risk to personnel. There are limited data available on the effects of exposure to aluminium phosphide on pregnancy and the unborn child. Aluminium phosphide may enter the environment from industry where it is created, stored, transported or disposed of. As it’s definitely red phosphorus that Walter is using the chemistry is not looking too good. Fumigation with phosphine gas is by far the most widely used treatment for the protection of stored grain against insect pests. It is very unlikely that the general population will be exposed to a level of aluminium phosphide high enough to cause adverse health effects. If shortness of breath occurs or breathing is difficult (dyspnea), administer oxygen. 0000003217 00000 n 0000002983 00000 n Phosphine is present as a gas at room temperature, so ingestion is unlikely. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B978012374367100104X, URL: https://www.sciencedirect.com/science/article/pii/B9780123864543001846, URL: https://www.sciencedirect.com/science/article/pii/B012227055X005411, URL: https://www.sciencedirect.com/science/article/pii/B978012386454300467X, URL: https://www.sciencedirect.com/science/article/pii/B9780123822390000030, URL: https://www.sciencedirect.com/science/article/pii/B978008044992000612X, URL: https://www.sciencedirect.com/science/article/pii/B9780123822390000078, URL: https://www.sciencedirect.com/science/article/pii/B9780444533494000856, URL: https://www.sciencedirect.com/science/article/pii/B9780080449920012347, URL: https://www.sciencedirect.com/science/article/pii/B9780080449920007100, Reproductive and Developmental Toxicology, 2011, Hayes' Handbook of Pesticide Toxicology (Third Edition), Encyclopedia of Toxicology (Third Edition), Encyclopedia of Food Sciences and Nutrition (Second Edition), Six-membered Rings with One Heteroatom, and their Fused Carbocyclic Derivatives, Polymer Science: A Comprehensive Reference, Eight-membered and larger Heterocyclic Rings and their Fused Derivatives, Other Seven-membered Rings, Six-membered Rings with Two Heteroatoms, and their Fused Carbocyclic Derivatives. Inhaling phosphine causes respiratory irritation, compromises heart (cardiac) and circulatory functions, depresses the central nervous system, and produces severe gastrointestinal pain. This site uses cookies from Google and other third parties to deliver its services, to personalise adverts and to analyse traffic. Phosphine in workplace atmospheres: OSHA-SLTC Method ID-180.

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